کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6605130 | 1424099 | 2017 | 27 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Intercalation of anions into graphite electrode from butylene carbonate in activated carbon/graphite hybrid capacitors
ترجمه فارسی عنوان
تداخل آنیون ها در الکترود گرافیت از کربنات بوتلن در خازن های هیبرید کربن فعال / گرافیت
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
The solvation of anions with organic solvent and its electrochemical intercalation into graphite is a significant research orientation in the electrochemical energy storage. Butylene carbonate (BC), a common solvent with higher oxidation resistance compared with ethylene carbonate (EC) and propylene carbonate (PC), is profitable in studying anion-graphite intercalation compounds (AGICs). In this paper, the electrochemical intercalation behaviors of three representative anions (BF4â, ClO4â and PF6â) in BC solution were studied and the solvation states of these anions were characterized by electrochemical in situ and ex situ techniques. The interpretation of results illuminated that all three anions were able to intercalate into graphite with the similar reversibility but different solvation state, and the conclusive role that solvent played in the intercalation process was also discovered.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 258, 20 December 2017, Pages 380-387
Journal: Electrochimica Acta - Volume 258, 20 December 2017, Pages 380-387
نویسندگان
Yuhao Huang, Li Qi, Hongyu Wang,