کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6608668 | 459541 | 2016 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Si/Ni3Si-Encapulated Carbon Nanofiber Composites as Three-Dimensional Network Structured Anodes for Lithium-ion Batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Si/Ni3Si-encapulated carbon nanofiber composites are synthesized by a facile one-pot electrospinning method and employed as three-dimensional network structured anode materials for lithium ion batteries. It is demonstrated that the composite exhibited increased cycling performance with a reversible capacity of 1132.4 mAh gâ1 after 200 cycles, which is 45% higher compared to the bare Si. The improved battery performance is attributed to the alloying of Si with Ni, which could effectively alleviate the volume expansion during lithium insertion/extraction. In addition, the formation of one dimensional nanofiber in which Si/Ni3Si nanoparticles are well distributed not only increases the electronic conductivity, but also enhances the mechanical strength of the electrodes, resulting in increased cycle stability.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 192, 20 February 2016, Pages 385-391
Journal: Electrochimica Acta - Volume 192, 20 February 2016, Pages 385-391
نویسندگان
Peixin Zhang, Liang Huang, Yongliang Li, Xiangzhong Ren, Libo Deng, Qiuhua Yuan,