کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6613676 | 459600 | 2014 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Study of the structural and thermal stability of Li0.3Co2/3Ni1/6Mn1/6O2
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Study of the structural and thermal stability of Li0.3Co2/3Ni1/6Mn1/6O2 Study of the structural and thermal stability of Li0.3Co2/3Ni1/6Mn1/6O2](/preview/png/6613676.png)
چکیده انگلیسی
Thermal and structural stabilities of the delithiated positive electrode material LixCo2/3Ni1/6Mn1/6O2were studied by X-ray diffraction, magnetic and thermogravimetric analysis. In the opposite to the classical electrode materials LiNiO2 and LiCoO2, the structural symmetry (S.G. R-3 m) of the starting material LiCo2/3Ni1/6Mn1/6O2 is preserved during the electrochemical cycling with a small variation of the unit cell parameters. Squid measurements evidenced that practically no Ni2+ ions were present in the lithium slab even after the lithium extraction process. For the thermal stability, the highly oxidized phase Li0.3Co2/3Ni1/6Mn1/6O2 was tested. This delithiated phase undergoes only 5.16% weight loss after heating up to 600 °C. This weight loss has no effect on the structure symmetry as the starting α-NaFeO2 type structure was preserved during the thermal treatment. The obtained results coupled to the excellent electrochemical features of LiCo2/3Ni1/6Mn1/6O2clearly showits ability to compete with the commercialized cathode materials
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 135, 20 July 2014, Pages 536-542
Journal: Electrochimica Acta - Volume 135, 20 July 2014, Pages 536-542
نویسندگان
Abdelfattah Mahmoud, Ismael Saadoune, Siham Difi, Moulay Tahar Sougrati, Pierre-Emmanuel Lippens, José Manuel Amarilla,