کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6614244 | 459623 | 2014 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The study of ferrocenium complexes-DNA interaction based on Langmuir-Blodgett films modified electrode
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کلمات کلیدی
(CV) - (رزومه)Langmuir–Blodgett - Langmuir-Blodgettglassy carbon electrode - الکترود کربن شیشه ایSaturated Calomel Electrode - الکترودهای کالومل اشباع شدهSurface pressure–area isotherm - ایزوترم سطح سطح فشارDifferential pulse voltammetry - ولتامتری پالس تفاضلیcyclic voltammograms - ولتیموگرافی دوره ای
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this paper, electrochemical method was used to investigate the interactions between DNA and amphiphilic ferrocenylimine. The method was developed using the system of electrode modified with the amphiphilic ferrocenylimine LB films. Electrochemical results obtained from amphiphilic ferrocenylimine LB films modified electrode suggested that the forrocenium derivative could interact strongly with dsDNA. It was observed that the binding of amphiphilic ferrocenylimine to DNA led to a significant peak current decrease of amphiphilic ferrocenylimine LB films modified electrode. The interactions between amphiphilic ferrocenylimine and four basic groups were also investigated, the results revealed that the basic groups cytosine, thymine and adenine could interact with forrocenium complex, but guanine showed no interaction with forrocenium complex. The order of interaction intensity for four basic groups with forrocenium complex (from strong to feeble) is cytosine > thymine > adenine > guanine. Therefore, the amphiphilic ferrocenylimine interacted with DNA through the basic groups cytosine, thymine and adenine.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 115, 1 January 2014, Pages 306-310
Journal: Electrochimica Acta - Volume 115, 1 January 2014, Pages 306-310
نویسندگان
Pingping Liu, Qiansi Chen, Huina Zhou, Baoxian Ye, Tiesheng Li,