کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6615057 | 459616 | 2013 | 31 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structural and electrochemical characterization of carbon electrode modified by multi-walled carbon nanotubes and surfactant
ترجمه فارسی عنوان
خصوصیات ساختاری و الکتروشیمیایی الکترودهای کربنی اصلاح شده توسط نانولوله های کربنی چندبخشی و سورفاکتانت
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کلمات کلیدی
نانولوله های کربنی چند دیواره، الکترود طیف سنجی امپدانس الکتروشیمیایی، ولتامتری سیسیک، مدل خط انتقال
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
In this study, multi-walled carbon nanotubes were successfully deposited on the surface of the carbon electrode (CE) using a cationic surfactant (Cetyl Trimethyl Ammonium Bromide, CTAB) by simple electrodeposition method. FT-IR spectra, SEM images and the contact angle measurements were employed to characterize the structure of the modified electrode. The electrochemical impedance spectroscopy and cyclic voltammetry were performed to evaluate the electroanalytical behavior of electrodes through the modification process. The results indicated that the impedance of the modified electrode was reduced about 95% at pH 3 and 7.4 and 91% at pH 11 due to the deposition of the nanotubes on its surface. The equivalent circuit for EIS measurements was perfectly fitted at three pH values (3, 7.4 and 11) on the basis of the transmission line model that represents the impedance response of a diffusion process to characterize the properties of the bulk films. Also, the electrochemical behavior of methylene blue on the surface of the modified electrode was investigated. The obtained cyclic voltammograms showed three redox peaks, which can be related to the formation of semi-methylene blue and leucomethylene blue.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 112, 1 December 2013, Pages 505-514
Journal: Electrochimica Acta - Volume 112, 1 December 2013, Pages 505-514
نویسندگان
Elmira Pajootan, Mokhtar Arami,