کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6658946 | 1425527 | 2018 | 31 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Extraction of vanadium from direct acid leaching solution of clay vanadium ore using solvent extraction with N235
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
Solvent extraction of vanadium from a direct acid leaching solution, generated by the direct leaching of clay vanadium ore, was conducted using tertiary amine N235, and the effects of the main factors on the extraction of vanadium and iron were investigated. Through a three-stage countercurrent extraction under the following optimum conditions: N235 concentration of 10% (v/v), initial aqueous phase pH of 1.8-2.0, phase ratio (A/O) of 2.5, and extraction time of 5â¯min, vanadium extraction efficiency reached above 98% whereas iron and other impurities were barely extracted. In addition, the solution chemical behavior of the vanadium extraction with N235 was analyzed. After oxidation and neutralization, V(IV) was oxidized to V(V), and VO2+ was converted to various forms of anions. N235, acidified by H2SO4 to convert R3N to (R3NH)2SO4, was able to extract vanadium through anion-exchange reaction. When vanadium was in the specific form of [H2V10O28]4â, high extraction efficiency was obtained, and vanadium was extracted more easily. As the pH increased, the concentration of [H2V10O28]4â and the dissociation of HSO4â also increased, which improved extraction efficiency. Vanadium existed in form of [H2V10O28]4â within a wide pH range of 1-3.5, but dissociation of (R3NH)2SO4 occurred at pHâ¯>â¯2.0, which hampered the extraction. Moreover, Fe(III) was precipitated by hydrolysis at pHâ¯>â¯2.0, which prevented the two phases from separating and caused a coprecipitation loss of vanadium.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Hydrometallurgy - Volume 177, May 2018, Pages 27-33
Journal: Hydrometallurgy - Volume 177, May 2018, Pages 27-33
نویسندگان
Guohua Ye, Yibo Hu, Xiong Tong, Lu Lu,