کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6664639 1427075 2018 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The effect of cleaning agents on the structural features of heat exchanger deposits from sugar factories
ترجمه فارسی عنوان
اثر مواد تمیز کننده بر ویژگی های ساختاری سپرده مبدل های حرارتی از کارخانه های شکر
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی
The removal of deposits from heat exchangers is one of the biggest challenges facing many food and chemical industries. Sodium hydroxide and acid cleaning are generally used on a regular basis to remove composite scale deposits from sugarcane factories. This paper evaluates the use of Fourier Transform Infrared (FTIR) spectroscopy, X-ray fluorescence, X-ray powder diffraction and 29Si nuclear magnetic resonance (NMR) to study the composition and the structural features of residual solid after NaOH treatment and use a second treatment of ethylene diamine tetraccetic acid tetra sodium salt (Na4EDTA) or dilute HCl to unravel the transformations of silica. There is no evidence of strong association between the silica matrix and the oxalates, or calcium carbonate components, but the use of dilute HCl resulted in the formation of complex and intractable Q3 [(OH)*Si(OSi)3] and Q4 [*Si(OSi)4] species as a consequence of re-organization/repolymerization processes. On the contrarily, the use Na4EDTA resulted in the formation of the simpler Q0 [Si(OH)4] 'and Q1 [(OH)3*Si(OSi)] species. However, when the deposit contains a high proportion of hydroxyapatite (Ca5(PO4)3OH), HCl is more effective than Na4EDTA. When a cleaning regime involves a two-step process the order of addition is important for effective removal of deposits.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Food Engineering - Volume 226, June 2018, Pages 65-72
نویسندگان
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