کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
68496 | 48515 | 2006 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Palladium-neocuproine catalyzed aerobic oxidation of alcohols in aqueous solvents
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
An overview is presented on the performance of Pd-complexes with phenanthroline-type ligands that are highly active catalysts for alcohol oxidation in water as well as in water/polar co-solvent mixtures. The mechanistic details of this intriguingly active and stable Pd-species are summarized. The (neocuproine)Pd(OAc)2 catalyst is unique in that it tolerates water, polar co-solvents and a wide variety of functional groups in the alcohol. Turnover frequencies of >1500 h−1 were achieved in the latter case and a series of alcohols was oxidized with 0.1–0.5 mol% of catalyst.
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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 251, Issues 1–2, 17 May 2006, Pages 246–254
Journal: Journal of Molecular Catalysis A: Chemical - Volume 251, Issues 1–2, 17 May 2006, Pages 246–254
نویسندگان
Isabel W.C.E. Arends, Gerd-Jan ten Brink, Roger A. Sheldon,