کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6974542 1453344 2015 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Optimization study of binary metal oxides catalyzed transesterification system for biodiesel production
ترجمه فارسی عنوان
مطالعه بهینه سازی اکسید فلزی باینری کاتالیزور سیستم ترانس اکسیداسیون برای تولید بیودیزل
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بهداشت و امنیت شیمی
چکیده انگلیسی
The focus of this study is to produce biodiesel using non-edible feedstock (Jatropha curcas oil) via heterogeneous base catalyzed transesterification reaction. The solid base catalysts, binary metal oxide (CaO-ZnO and CaO-La2O3) were selected for the transesterification of high acid jatropha oil. Furthermore, the design of experiments was performed using 5-level-4 factor central composite design coupled with response surface methodology (RSM) in order to optimize the transesterification conditions. Four process factors were evaluated: (1) reaction time (1-5 h), (2) methanol/oil molar ratio (15:1-30:1), (3) reaction temperature (40-200 °C) and (4) catalyst loading (1-5 wt.%). Based on the quadratic model generated from RSM, reaction temperature rendered the most significant effect for both CaO-ZnO and CaO-La2O3 catalyzed reactions, followed by catalyst loading and reaction time. Besides, both reaction models showed that interaction between reaction temperature with reaction time and catalyst loading has positively influenced the biodiesel yield. The highest conversion predicted for CaO-ZnO and CaO-La2O3 catalyzed reactions was 97.03% and 96.27%, respectively, with reasonable predictability and sufficient accuracy data (small error: 0.33-0.34%). Furthermore, the physicochemical characteristics of produced biodiesel were tested with compliance to ASTM D7851 and EN 14124.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Process Safety and Environmental Protection - Volume 94, March 2015, Pages 430-440
نویسندگان
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