کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
73818 49072 2013 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Layer-by-layer loading iron onto mesoporous silica surfaces: Synthesis, characterization and application for As(V) removal
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Layer-by-layer loading iron onto mesoporous silica surfaces: Synthesis, characterization and application for As(V) removal
چکیده انگلیسی

Iron-bearing minerals have been used as adsorbents for arsenic anions for many decades, but both the small surface area and the poorly defined pore structure limit their performance in removal of arsenic from aqueous systems. Herein, we report a sonochemical layer-by-layer (LBL) loading process for depositing of ferric species onto mesoporous silicas (i.e., MCM-41, SBA-15, and KIT-6). The surface area, pore size and volume, as well as the iron loading of these mesoporous silicas can be tailored and optimized with increasing in loading cycle via a LBL protocol. The surface functioned materials were characterized by X-ray diffraction (XRD), N2 physisorption, transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectrometry and zeta potential measurement. Their performance in As(V) adsorption was also tested. The results indicate that the iron-loaded mesoporous silicas retained their ordered pore structure as well as the large surface area, which enable them a good kinetic performance in uptake of As(V) anions. When iron loading is as much as 10 wt.%, two representative iron-loaded silicas Fe10MCM-41 and Fe10KIT-6, exhibited the best performance in trapping the As(V) anions, with an Fe/As molar ratio of about 5.77 and 5.10, respectively. The Fe/As molar ratio implies they belong to the iron-containing adsorbents with the highest adsorption performance for As(V), and therefore could be used as alternative adsorbents for As(V) adsorption.

A sonochemical layer-by-layer (LBL) loading procedure was adopted in surface functionalization of three mesoporous silicas (i.e., MCM-41, SBA-15, and KIT-5) with iron species. The loading of iron onto the host silicas is tunable by varying the LBL loading cycles. The obtained iron-loaded mesoporous materials perform very well in adsorption of arsenate from aqueous solution.Figure optionsDownload as PowerPoint slideHighlights
► Iron-loaded mesoporous silicas were prepared via the sonochemical LBL loading process.
► The structure of iron-loaded silicas is tunable and easily optimized for adsorption of As(V).
► The iron-loaded mesoporous silicas perform very well in adsorption of As(V).

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 171, 1 May 2013, Pages 139–146
نویسندگان
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