Gold nanoparticles supported on periodic mesoporous organosilicas for epoxidation of olefins: Effects of pore architecture and surface modification method of the supports

Periodic mesoporous organosilicas (PMOs), namely MCM-41, MSU, and SBA-15 ordered mesoporous silicas (OMSs) incorporated with bridging disulfide-ionic liquid moieties prepared either by the one-pot or the post-synthesis procedure, were used as supports for the gold nanoparticle (GNP) catalysts. The catalytic properties of various supported GNP/PMO catalysts were evaluated by epoxidation reaction of various olefins. It was found that the pore architectures of the PMO materials as well as the method by which organic moieties were incorporated onto the mesoporous silica materials play crucial roles in the particle size and dispersion of the GNPs which, in turn, dictate the catalytic performances of the supported GNP/PMO catalysts. In comparison with those synthesized by the one-pot procedure, PMO materials prepared by the post-synthesis method are more favorable in terms of dispersion of GNPs. Moreover, PMOs originated from OMSs with one-dimensional (1-D) pore structures also exhibit better GNP dispersions and catalytic activities than those with three-dimensional (3-D) pore architectures. This has been ascribed due to the restricted Ostwald ripening and/or migration-coalescence of the GNPs between adjacent pores of the PMOs with 1-D pore structures.

The catalytic performances of gold nanoparticles (GNPs) supported on various periodic mesoporous organosilicas (PMOs) surface-modified with organic bridged silsesquioxane (OBSQ) moieties during epoxidation of α-pinene and various olefins were evaluated.Figure optionsDownload as PowerPoint slideHighlights
► Catalytic properties of supported gold nanoparticles (GNPs) catalysts were studied.
► Various periodic mesoporous organosilica (PMO) supports were examined.
► Performances of GNP/PMO catalysts during expoxidation of olefins were compared.
► Post-synthesized PMOs with 1D structure possesses better performances.
► Wide applications in olefin expoxidation over such GNP/PMO catalysts are inferred.