کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7619841 | 1494474 | 2018 | 21 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Far UV peaks contribute for identification of carotenoids E/Z isomers
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
By using iodine-catalyzed photoisomerization, and HPLC-DAD, we found that were: in the spectrum of each carotene there is a “far UV peak”, which maintains the maximum in all its E/Z isomers and this maximum it is different from E/Z isomers of other carotene. The values of these absorption maxima 294-296â¯nm for lycopene E/Z isomers; 266-269â¯nm for α-carotene E/Z isomers; 273-276â¯nm for β-carotene E/Z isomers; 281-283â¯nm for γ-carotene E/Z isomers; and 280-282â¯nm for γ-carotene E/Z isomers. These UV absorption peaks are highly valuable to determine which components are geometrical isomers of the same carotene, since that not only the maximum absorbance is specific for each carotene, but also the shapes of these peaks are clearly different. The utility of this “far UV peak” was tested, by identifying Z isomers in Bactris gasipaes fruit. We found that two carotenoids previously identified as all-E-δ-carotene and Z-γ-carotene, are actually Z-γ-carotene and Z-lycopene respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Food Composition and Analysis - Volume 67, April 2018, Pages 159-162
Journal: Journal of Food Composition and Analysis - Volume 67, April 2018, Pages 159-162
نویسندگان
Enrique Murillo,