کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7720851 | 1497506 | 2014 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and electrocatalytic alcohol oxidation performance of Pd-Co bimetallic nanoparticles supported on graphene
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کلمات کلیدی
SCEDMFCsECSAChronoamperometryrGO - RGOElectrocatalysts - الکترو کاتالیزورهاSaturated Calomel Electrode - الکترودهای کالومل اشباع شدهAlcohol oxidation - اکسید کردن الکل، اکسایش الکلGraphene oxide - اکسید گرافنReduced graphene oxide - اکسید گرافن کاهش یافته یا اکسید گرافن کاهیدهElectrochemically active surface area - سطح الکتروشیمیایی فعالDirect ethanol fuel cells - سلول های سوخت مستقیم اتانولDirect methanol fuel cells - سلول های سوخت مستقیم متانولCyclic voltammetry - ولتامتری چرخهایPalladium - پالادیوم یا پالادیمFuel cells - پیل های سوختیCobalt - کبالتGraphene - گرافن
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Magnetic Pd-Co bimetallic nanoparticles supported on reduced graphene oxide sheets (Pd-Co/RGO) with excellent electrocatalytic performance have been synthesized by a rapid reducing method, using sodium hypophosphite as the reducing agent. The loading and crystalline phase of cobalt in the Pd-Co/RGO hybrids varied as to the initial amount of cobalt salt and reducing agent. Transmission electron microscopy images show that the mean size of the Pd-Co bimetallic nanoparticles was about 10-13Â nm and without significant agglomeration. At the same Pd loading on graphene, the current densities of the forward anodic peak of the different Pd-Co/RGO catalysts was decreased by about 25% when compared with that of the pure Pd nanoparticles supported on reduced graphene oxide for both methanol and ethanol oxidation. However, chronoamperometry tests confirmed that the stability was increased by up to 240% and 225% for methanol oxidation and ethanol oxidation, respectively. It is hypothesized that the Co layer on Pd partially blocks Pd sites sacrificing a small portion of the activity of the catalysts, but it leaves the remaining Pd more active and thus enhances alcohol oxidation kinetics and tolerance to poisoning intermediates. Catalytic performance of the Pd-Co/RGO hybrids for alcohol oxidation is primarily affected by the interaction among Pd, Co, and graphene.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 3, 16 January 2014, Pages 1325-1335
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 3, 16 January 2014, Pages 1325-1335
نویسندگان
Yan Wang, Yan Zhao, Jian Yin, Muchun Liu, Qi Dong, Yuqin Su,