Stereoregularity evolution of isobornyl acrylate and styrene copolymers by 2D NMR spectroscopy

A comprehensive microstructure analysis of poly(isobornyl acrylate-co-styrene), synthesized by ATRP using CuBr/PMDETA catalyst system, has been done by correlation of 1D (1H, 13C{1H}, DEPT) and 2D (HSQC, TOCSY, HMBC) NMR spectroscopy.