کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7840102 | 1505864 | 2018 | 30 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Photophysical behavior of some thymol based schiff bases using absorption and fluorescence spectroscopy
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
The absorption and fluorescence spectra of some biologically active thymol based Schiff bases have been studied at room temperature in a series of solvents of varying polarity. The solvent effect on the spectral properties of Schiff bases has been analyzed using Reichardt and Kawski equations and Kamlet-Taft and Catálan multi-parametric solvent polarity scales. The substituents and the solvents strongly influence the excited state behavior of these molecules owing to different electronic arrangements. The excited state dipole moments ( μe/μg and Îμ) of these molecules have been calculated using solvatochromic shift methods based on bulk solvent polarity functions f (ε,n) and Ï (ε,n) and microscopic solvent polarity parameter ETN, respectively. The increase in excited state dipole moments (μe) indicates a more polar excited state and intramolecular charge transfer (ICT) characteristics of these molecules. The molecular orbitals (HOMO-1, HOMO, LUMO and LUMO+â¯1) and molecular electrostatic potential (MEP) surfaces have been generated from their optimized geometries using semi-empirical (PM3) calculations to account for electronic excitations and changes in the overall charge distribution of Schiff bases. The Taft and Catalán multi-parametric equations used in the interpretation of the specific solute-solvent interactions reveal that the most important contribution to the solute-solvent interaction in the excited state comes from the hydrogen-bond acceptor capacity of the solvent.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Luminescence - Volume 198, June 2018, Pages 92-102
Journal: Journal of Luminescence - Volume 198, June 2018, Pages 92-102
نویسندگان
Ritu Payal, Manju K. Saroj, Neera Sharma, Ramesh C. Rastogi,