کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8083293 | 1521607 | 2013 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Stable and selective scintillating anion-exchange sensors for quantification of 99TcO4â in natural freshwaters
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی هسته ای و مهندسی
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چکیده انگلیسی
New dual functionality scintillating anion-exchange resins were developed for selective determination of 99TcO4â in various natural freshwater samples. Stable scintillating particles were formed by preparing the vinyl monomer 2-[4-(4â²-vinylbiphenylyl)]-5-(4-tert-butylphenyl)-1,3,4-oxadiazole (vPBD), starting with the commercial organic flour TBut-PBD and its subsequent copolymerization with styrene, divinylbenzene, and p-chloromethylstyrene mixture. To integrate the radiochemical separation and radiometric detection steps within the same bead, the chloromethyl groups of the scintillating resins were subjected to amination reactions with dioctylamine (DOA) and trioctylamine (TOA). On-line quantification of 99TcO4â was achieved by packing the scintillating anion-exchange resin into Teflon tubing for quantification by a flow scintillation analyzer (FSA). The two functionalized resins were selective for pertechnetate over the common anions in natural freshwaters, especially Clâ and SO42â with up to 1000Â ppm and with up to 10Â ppm Iâ and Cr2O72â. The uptake efficiency of the TOA sensor decreased from 97.88% to 85.08% in well water and river water, respectively, while the counting efficiency was almost constant (69.50%). The DOA performance showed lower efficiency in the two water types relative to TOA. On the other hand, the DOA sensor could be regenerated by 5Â M HNO3 for reuse at least four times without losing its chemical or optical performance. The detection limit was 1.45Â Bq which could be achieved by loading 45Â mL from well and tap water containing the maximum contaminant level (MCL) of 99Tc (33Â Bq/L).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Environmental Radioactivity - Volume 126, December 2013, Pages 156-164
Journal: Journal of Environmental Radioactivity - Volume 126, December 2013, Pages 156-164
نویسندگان
Ayman F. Seliman, Kerttuli Helariutta, Szymon J. Wiktorowicz, Heikki Tenhu, Risto Harjula,