کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9452068 | 1307858 | 2005 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dechlorination of polychlorinated organic compounds by electrochemical reduction with naphthalene radical anion as mediator
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کلمات کلیدی
موضوعات مرتبط
علوم زیستی و بیوفناوری
علوم محیط زیست
شیمی زیست محیطی
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چکیده انگلیسی
Electrochemical reduction with electrochemically generated naphthalene radical anion in N,N-dimethylformamide was applied to the dechlorination of five representative POPs, namely HCB, lindane, DDT, PCP and aldrin. Rapid and complete dechlorination was possible for lindane and DDT to give nearly quantitative yields of benzene and 1,1-diphenylethane, respectively. HCB was reduced through complex reaction pathways to yield unknown products. Dechlorination of PCP and aldrin beyond dichlorinated compounds was difficult because of their very negative reduction potential. The reaction pathways for each dechlorination were proposed with the identification of intermediates.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemosphere - Volume 59, Issue 10, June 2005, Pages 1487-1496
Journal: Chemosphere - Volume 59, Issue 10, June 2005, Pages 1487-1496
نویسندگان
Atsushi Matsunaga, Akio Yasuhara,