کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9609779 | 46537 | 2005 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation, structural characterization and photocatalytic activity of mesoporous Ti-silicates
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Both the Ti incorporation method (IMP or CP) and TiO2 content (4.7-35.0 wt.%) had large effects on structural characteristics and photocatalytic activity of Ti-silicates, whereas no important effects were observed with respect to calcination temperature (200-600 °C). At all conditions, TiO2 was present as pure anatase crystallites with particle diameters in IMP catalysts of 4.4-7.0 nm, being clearly smaller than those in CP ones (12.0-19.6 nm). The ordered structure of the silica was at least partially preserved up to a TiO2 content of 25 wt.% (CP) and 33 wt.% (IMP). With increasing TiO2 content, specific surface area (SSA 376-805 m2 gâ1) of both CP and IMP catalysts decreased. Similar trends were observed for pore volumes (0.6-1.2 mL gâ1) and pore diameters (4.5-7.5 nm) in IMP catalysts. Initial photocatalytic TCE degradation rate constants (0.014-0.202 minâ1) obtained with CP catalysts increased systematically with TiO2 contents up to 35 wt.%, while in IMP ones, they levelled off at TiO2 contents above 17 wt.%. TCE degradation rates obtained with CP catalysts were up to a factor of six higher than those measured applying the IMP method. This may be explained by a different TiO2 localization in the silica structure. During IMP preparation, TiO2 is mostly incorporated within the silica mesopores, whereas during CP synthesis, it is mainly localized on the external silica surface.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis B: Environmental - Volume 61, Issues 1â2, 27 October 2005, Pages 47-57
Journal: Applied Catalysis B: Environmental - Volume 61, Issues 1â2, 27 October 2005, Pages 47-57
نویسندگان
Gyula Wittmann, Kristof Demeestere, András Dombi, Jo Dewulf, Herman Van Langenhove,