کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9749284 1493806 2005 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Cationic surfactant-based polyfluorate salts: Phase separation and analytical applications in the extraction and preconcentration of ionic species prior to liquid chromatography
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Cationic surfactant-based polyfluorate salts: Phase separation and analytical applications in the extraction and preconcentration of ionic species prior to liquid chromatography
چکیده انگلیسی
The liquid-solid phase separation originating from the formation of cationic surfactant-based polyfluorate salts (CSBPS) has been explored for extracting and preconcentrating ionic species. Two cationic surfactants were tested; one with aliphatic hydrocarbon tail [Cetyltrimethylammonium bromide (CTAB)]and the other containing a heterocyclic ring [Hexadecylpyridinium bromide (HPyBr)]. Phase separation possibility was investigated with the use of hexafluorophosphates (PF6−) and tetrafluoroborates (BF4−). The effect of added acid, base and salt on the phase separation and analyte extraction was also investigated. In all cases the obtained phase diagrams consisted of two regions: a homogeneous liquid region and a solid-liquid region. Analytes of hydrophilic and hydrophobic nature such as amines, amino acids and organic chromophores were used as test compounds in both their anionic and cationic forms. The respective recoveries ranged from over 90% for anionic species and in the proximity of 50% for cationic species, remaining below 20% for neutral species. Extracts from alkaline aqueous and plasma samples spiked with tyrosine and phenylalanine were also subjected to HPLC separation with UV detection with satisfactory results. On line application was also enabled using a flow through-solid phase extraction-HPLC hyphenated apparatus, thus adding the element of automatization and increased reproducibility.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Chromatography A - Volume 1066, Issues 1–2, 25 February 2005, Pages 19-25
نویسندگان
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