Stereoselectivity of model C22-23 aldol coupling for spirangiens A & B
Keywords: Polyketide; Spiroacetal; Aldol reaction; Cytotoxic; Spirangien;
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Detection of soluble co-factor dependent protein expression in vivo: Application to the 4â²-phosphopantetheinyl transferase PptT from Mycobacterium tuberculosis
Keywords: ACP; acyl carrier protein; AcpS; acyl carrier protein synthase; AnTet; anhydrotetracycline; BSA; bovine serum albumin; CoA; Coenzyme A; DHFR; dihydrofolate reductase; DSF; differential scanning fluorimetry; DTT; dithiothreitol; GFP; green fluorescent prot
Stereoselective synthesis of the C13-32 spiroacetal fragment of spirangien A
Keywords: Polyketide; Spiroacetal; Aldol reaction; Cytotoxic; Spirangien;
Recombinant strains for the enhanced production of bioengineered rapalogs
Keywords: Rapamycin; Polyketide; Bioengineering
Genome sequence of the plant growth promoting strain Bacillus amyloliquefaciens subsp. plantarum B9601-Y2 and expression of mersacidin and other secondary metabolites
Keywords: Genome sequence; Bacillus amyloliquefaciens subsp. plantarum; Plant growth promotion; Rhizobacterium; Nonribosomal synthesis; Lipopeptide; Polyketide; Mersacidin
Antiangiogenic effects of marine sponge derived compounds on cancer
Keywords: Anti-angiogenesis; Sponge; Alkaloids; Cancer; Metastasis; Polyketide
Effect of aposymbiotic conditions on colony growth and secondary metabolite production in the lichen-forming fungus Ramalina dilacerata
Keywords: Growth medium pH; Mycobiont; PKS gene expression; PKS paralog; Polyketide;
Identification of 8-amino-2,5,7-trihydroxynaphthalene-1,4-dione, a novel intermediate in the biosynthesis of Streptomyces meroterpenoids
Keywords: Isoprenoid; Terpenoid; Polyketide; Polyketide synthase; Aminotransferase;
A polyketide metabolite from the fungicolous Nodulisporium sp. SH-1
Keywords: Fungicolous; Nodulisporium sp.; Hemiacetal; Polyketide;
Ketoolivosyl-tetracenomycin C: A new ketosugar bearing tetracenomycin reveals new insight into the substrate flexibility of glycosyltransferase ElmGT
Keywords: Glycosyltransferase; Ketosugar; Elloramycin; Combinatorial biosynthesis; Streptomyces; Polyketide
Genome mining reveals the evolutionary origin and biosynthetic potential of basidiomycete polyketide synthases
Keywords: Basidiomycetes; Polyketide; Secondary metabolism; Genome mining; Orsellinic acid; Evolution
Mycoepoxydiene, a fungal polyketide inhibits MCF-7 cells through simultaneously targeting p53 and NF-κB pathways
Keywords: Mycoepoxydiene; Polyketide; ROS; p53; NF-κB
Identification of gene clusters associated with fusaric acid, fusarin, and perithecial pigment production in Fusarium verticillioides
Keywords: Secondary metabolism; Polyketide; Fusarium verticillioides; Microarray analysis; Fusaric acid
Phylogenomic and functional domain analysis of polyketide synthases in Fusarium
Keywords: Fusarium; Microarray; Phylogenomic analysis; Polyketide; Secondary metabolites
Recent advances in antitubercular natural products
Keywords: Natural products; Terpene; Alkaloid; Polyketide; Peptide; Antitubercular
The fungal treasure chest: Spore origins?
Keywords: Polyketide; Secondary metabolite; Spore
Polyketide derivatives of endophytic fungus Pestalotiopsis sp. isolated from the Chinese mangrove plant Rhizophora mucronata
Keywords: Endophytic fungus; Pestalotiopsis sp.; Polyketide; Structure identification;
Chemical scaffolds with structural similarities to siderophores of nonribosomal peptide–polyketide origin as novel antimicrobials against Mycobacterium tuberculosis and Yersinia pestis
Keywords: Nonribosomal peptide; Polyketide; Siderophore; Mycobacterium tuberculosis; Yersinia pestis; Antimicrobial compound; Pyrazoline; Hydroxyhydrazine
Palmerolide macrolides from the Antarctic tunicate Synoicum adareanum
Keywords: Melanoma; V-ATPase inhibitor; Polyketide;
Biosynthesis of the apoptolidins in Nocardiopsis sp. FU 40
Keywords: Polyketide; Type I polyketide synthase; Macrolide natural product; Gene cluster; Mutasynthesis;
Mupirocin F: structure elucidation, synthesis and rearrangements
Keywords: Selective oxidation; Polyketide; Rearrangements; Structure elucidation;
On the origins and biosynthesis of tetrodotoxin
Keywords: Tetrodotoxin (TTX); Toxin biosynthesis; Polyketide; Non-ribosomal peptide; Amidinotransferase
Untenolide A, a new polyketide from an Okinawan marine sponge Plakortis sp.
Keywords: Sponge; Plakortis sp.; Polyketide; Untenolide A;
Prorocentin-4, a novel linear polyketide from a marine dinoflagellate Prorocentrum sp.
Keywords: Polyketide; Marine dinoflagellates; Prorocentrum sp.; Prorocentin-4;
Novel carbon-bridged citrinin dimers from a volcano ash-derived fungus Penicillium citrinum and their cytotoxic and cell cycle arrest activities
Keywords: Penicillium citrinum; Citrinin; Polyketide; Cytotoxicity; Cell cycle arrest;
Mycoepoxydiene, a fungal polyketide, induces cell cycle arrest at the G2/M phase and apoptosis in HeLa cells
Keywords: Mycoepoxydiene; Polyketide; G2/M arrest; MAPK; Apoptosis
Production of tetraketide lactones by mutated Antirrhinum majus chalcone synthases (AmCHS1)
Keywords: Antirrhinum majus; Chalcone synthase; Polyketide; p-coumaroyltriacetic acid lactone
Total synthesis of (+)-crocacin C
Keywords: Total synthesis; Crocacin; Polyketide
Spirastrellolide studies. Synthesis of the C(1)-C(25) southern hemispheres of spirastrellolides A and B, exploiting anion relay chemistry
Keywords: Spirastrellolide; Anion relay chemistry; Brook rearrangement; Stereoselective Spirocyclization; Petasis-Ferrier reaction; Dithiane; Multicomponent reaction; Spiroketal; Natural product; Polyketide; Total synthesis;
Computational analysis of phenotypic space in heterologous polyketide biosynthesis—Applications to Escherichia coli, Bacillus subtilis, and Saccharomyces cerevisiae
Keywords: FBA; MoMA; Polyketide; Metabolic engineering
Biosynthesis of toxic naturally-occurring seafood contaminants
Keywords: Toxin biosynthesis; Polyketide; Polyether; Ciguatoxin; Saxitoxin; Tetrodotoxin; Brevetoxin; Marine algae; Harmful algal blooms; Cyanobacteria; Nonribosomal peptide
Bionectriol A, a polyketide glycoside from the fungus Bionectria sp. associated with the fungus-growing ant, Apterostigma dentigerum
Keywords: Polyketide; Glycoside; Fungus-growing ant;
Applying Parallel Factor Analysis models to HPLC diode array detector datasets reveals strain dependent regulation of polyketide biosynthesis in Fusarium graminearum, Fusarium culmorum and Fusarium pseudograminearum
Keywords: Fusarium; Secondary metabolites; Polyketide; Polyketide synthase; High Performance Liquid Chromatography; Parallel Factor Analysis; Global transcription factors;
Decoding and engineering tetracycline biosynthesis
Keywords: Tetracycline; Polyketide; Antibiotic resistance; Streptomyces
Evolution of metabolic diversity: Insights from microbial polyketide synthases
Keywords: Polyketide; Evolution; Metabolic diversity; Recombination;
High titer production of tetracenomycins by heterologous expression of the pathway in a Streptomyces cinnamonensis industrial monensin producer strain
Keywords: Heterologous expression; Tetracenomycin; Precursor supply; Polyketide; Monensin; Crotonyl-CoA reductase; StreptomycesCCR, crotonyl-CoA reductase; DEBS, 6-deoxyerythronolide B synthase; PKS, polyketide synthase; TCM, tetracenomycin
The ABC transporter ATR1 is necessary for efflux of the toxin cercosporin in the fungus Cercospora nicotianae
Keywords: ABC transporter; Cercospora nicotianae; Cercosporin; Efflux pump; MFS transporter; Polyketide; Cercosporin production; Cercosporin resistance;
Cyathuscavins A, B, and C, new free radical scavengers with DNA protection activity from the Basidiomycete Cyathus stercoreus
Keywords: Cyathus stercoreus; DNA protection; Free radical scavenger; Polyketide
The biosynthesis of sorbicillinoids in Trichoderma sp. USF-2690: prospect for the existence of a common precursor to sorbicillinol and 5-epihydroxyvertinolide, a new sorbicillinoid member
Keywords: 5-Epihydroxyvertinolide; Trichoderma sp. USF-2690; Sorbicillinoids; Polyketide; Biosynthesis; Bisorbicillinoids;
Chemoenzymatic syntheses of prenylated aromatic small molecules using Streptomyces prenyltransferases with relaxed substrate specificities
Keywords: Enzyme catalysis; Prenylation; Flavonoid; Polyketide; Kinetics
Synthetic efforts towards the marine polyketide peloruside A
Keywords: Peloruside A; Marine; Polyketide; Synthesis; Tubulin
Deletion of a MFS transporter-like gene in Cercospora nicotianae reduces cercosporin toxin accumulation and fungal virulence
Keywords: Gene cluster; Polyketide; Split marker
Assignment of 13C NMR spectrum for blepharismin C based on biosynthetic studies
Keywords: Blepharismin; Phenanthroperylene quinone; Polyketide; INADEQUATEÂ spectrum;
New pentaenes from the sponge-derived marine fungus Penicillium rugulosum: structure determination and biosynthetic studies
Keywords: Penicillium; Natural product; Polyketide; Biosynthesis;
Musanahol: a new aureonitol-related metabolite from a Chaetomium sp.
Keywords: Polyketide; Ascomycota; Chaetomium sp; Absolute configuration; Mosher ester; Musanahol; Antibacterial;
Improving simvastatin bioconversion in Escherichia coli by deletion of bioH
Keywords: Biocatalysis; Keio collection; Polyketide; Simvastatin; Green chemistry
Long-chain multiple methyl-branched fatty acid-containing lipids of Mycobacterium tuberculosis: Biosynthesis, transport, regulation and biological activities
Keywords: Acyltrehaloses; Phthiocerol dimycocerosates; Sulfatides; Polyketide; Tuberculosis; Mycobacterium
Crystal Structures of Two Aromatic Hydroxylases Involved in the Early Tailoring Steps of Angucycline Biosynthesis
Keywords: PHHY, phenol hydroxylase; pHBH, para-hydroxybenzoate hydroxylase; MHBH, 3-hydroxybenzoate hydroxylase; r.m.s.d., root-mean-square deviation; MAD, multiple-wavelength anomalous diffractionFAD; angucycline; polyketide; aromatic hydroxylase; enzyme mechanism
Leptostatin: A synthetic hybrid of the cytotoxic polyketides callystatin A and leptomycin B
Keywords: Chiral allenylstannane; Cytotoxic compounds; Diastereoselective additions; Polyketide; Colon cancer; Lactone
Separation of anti-angiogenic and cytotoxic activities of borrelidin by modification at the C17 side chain
Keywords: Borrelidin; Polyketide; Angiogenesis inhibitor; Biosynthetic engineering