کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1448023 | 988662 | 2009 | 8 صفحه PDF | دانلود رایگان |

Since the structural integrity of A2B2O7-type pyrochlores relies mostly on the interconnecting BO6 octahedra, Ti4+ was selected to partially substitute Zr4+ in Gd2Zr2O7 in order to distort the pyrochlore structure in order to improve the material’s thermophysical properties for potential use as high-temperature thermal insulation. As evidenced by X-ray diffraction and Raman spectroscopy studies, incorporation of Ti4+ simultaneously leads to long-range ordering of the pyrochlore structure as well as local lattice distortion. These two effects have been shown to be competitive in determining the crystal energy of the Gd2(Zr1−xTix)2O7 series and result in a minimum value of the Young’s modulus at x = 0.3 and a maximum value of the coefficient of thermal expansion at x = 0.2. At lower temperatures, the thermal conductivity of Gd2Zr2O7 was significantly reduced by Ti4+ doping, and its composition dependence was accurately modeled by taking into account the phonon scattering by mass and strain fluctuations at the B site.
Journal: Acta Materialia - Volume 57, Issue 16, September 2009, Pages 4782–4789