کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1663843 1517995 2016 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of precursor stacking order and sulfurization temperature on compositional homogeneity of CZTS thin films
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Effect of precursor stacking order and sulfurization temperature on compositional homogeneity of CZTS thin films
چکیده انگلیسی


• Cu2ZnSnS4 films were grown on Mo-coated glass using DC magnetron sputtering and RTP.
• Metallic stacking orders and growth temperatures were varied.
• Modified metallic precursor layer (Cu/Sn/Zn/Cu) improved homogeneity of the film.High reaction temperature enhanced crystalline structure and homogeneity of the film.

In this study, Cu2ZnSnS4 (CZTS) absorber layers were grown by sequential deposition of metallic Cu, Zn, and Sn layers by DC magnetron sputtering on Mo coated glass followed by annealing in sulfur atmosphere in a rapid thermal processing (RTP) system for 3 min at 500 °C, 550 °C and 600 °C. Two different metal stacking sequences were investigated: Mo/Zn/Sn/Cu and Mo/Cu/Sn/Zn/Cu – both with a Cu-poor and Zn-rich composition. For the Mo/Cu/Sn/Zn/Cu stack, the initial Mo/Cu/Sn layer was pre-annealed to yield homogeneous CuSn alloys on which Zn and the final Cu was deposited afterwards. Compositional inhomogeneities were studied by measuring X-ray fluorescence (XRF) before and after KCN etching of the sulfurized samples as well as by glow discharge optical emission spectroscopy (GDOES). Additionally, crystallographic properties were analyzed by X-ray diffraction (XRD) and Raman spectroscopy. For the Mo/Zn/Sn/Cu precursor, we find that the initial stacking order is partially preserved with a Cu-rich surface and a Zn-rich bottom. In contrast, the modified stacking Mo/Cu/Sn/Zn/Cu leads to an improved compositional homogeneity. While a Zn-rich composition is still found at the bottom part of the film, after sulfurization for 3 min at 600 °C the surface and bulk part show homogeneous element distributions close to that of CZTS.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thin Solid Films - Volume 615, 30 September 2016, Pages 402–408
نویسندگان
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