کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1665641 | 1518050 | 2014 | 4 صفحه PDF | دانلود رایگان |
• Multi-photon sensitized polymerization of 3,4-ethylenedioxythiophene (EDOT).
• Three-dimensional microstructures of poly(EDOT) in the transparent polymer sheet.
• The dimeric compound of EDOT was employed as the starting material.
• The lateral precision of this system exceeded the diffraction limit.
A dimeric compound of 3,4-ethylenedioxythiophene was polymerized to form poly(3,4-ethylenedioxythiophene) by multi-photon sensitized polymerization using a femtosecond laser. In contrast, photopolymerization could not be achieved using 3,4-ethylenedioxythiophene as the starting material, because it has a more positive oxidation peak potential compared to the redox potential of the tris(2,2′-bipyridyl)ruthenium complex used as the photosensitizer. Furthermore, three-dimensional micropatterns of poly(3,4-ethylenedioxythiophene) could be produced in a transparent polymer sheet by scanning the laser focal point.
Journal: Thin Solid Films - Volume 554, 3 March 2014, Pages 102–105