کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1666743 | 1518084 | 2012 | 4 صفحه PDF | دانلود رایگان |
We report on hybrid light-emitting devices (HLEDs) based on CdSe/ZnS quantum dots in polymer matrices. Color purity of the HLED with a mixed matrix consisting of polyvinylcarbazole (PVK) and 2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole (PBD) improves with the increasing concentration of PBD. We attribute this improvement to the increased electron mobility of the matrix. By using an n-type cyano-containing polymer derived from 6-(3,6-dibromo-9H-carbazol-9-yl)hexanenitrile and tetraphenylsilane to replace PVK:PBD as the matrix, further pure red emission with Commission Internationale De L'Eclairage coordinates of (0.67, 0.33) and maximum external quantum efficiency of 2.51% has been achieved.
► The impact of host upon electroluminescence of CdSe/ZnS quantum dots was studied.
► Increased host electron-transporting improves the color purity of CdSe/ZnS.
► Pure emission with higher efficiency was achieved with an n-type polymer.
Journal: Thin Solid Films - Volume 520, Issue 24, 1 October 2012, Pages 7153–7156