کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1667360 | 1008849 | 2012 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Improved barrier performance of metal alkoxide-modified methyltrimethoxysilane films
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Improved barrier performance of metal alkoxide-modified methyltrimethoxysilane films Improved barrier performance of metal alkoxide-modified methyltrimethoxysilane films](/preview/png/1667360.png)
چکیده انگلیسی
Homogeneously modified methyltrimethoxysilane (MTMS) films used as the barrier layers were fabricated on stainless steel substrates by introducing only very low amount of metal alkoxide, e.g. tetrabutyl orthotitanate or tetrabutyl orthozirconate into the silane/ethanol/water precursors. The modified films exhibit tremendous improvement in their barrier performance, along with higher compactness, hydrophobicity and thickness. Solution analysis of the silane precursors indicated that both the hydrolysis and condensation reactions of MTMS were significantly facilitated in the presence of metal alkoxide. A schematic description for the promoted formation of metal alkoxide-modified silane films which is in accordance with our findings is given.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thin Solid Films - Volume 520, Issue 6, 1 January 2012, Pages 2052–2059
Journal: Thin Solid Films - Volume 520, Issue 6, 1 January 2012, Pages 2052–2059
نویسندگان
Ya-Qin Yang, Liang Liu, Ji-Ming Hu, Jian-Qing Zhang, Chu-Nan Cao,