کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1669055 | 1008878 | 2011 | 6 صفحه PDF | دانلود رایگان |
The paper presents a two-dimensional simulation study of a polycrystalline Cu(In,Ga)Se2 (CIGS) solar cell with various shapes of grains inside the CIGS absorber layer. The grain boundaries (GBs) with a diverse valence-band offset (VBO) and the density of defect states (NtA) are considered so as to evaluate their effects on the performance of the CIGS cell. The numerical simulations show that a CIGS cell with column-like grains can achieve a high conversion efficiency (η), while the η of a CIGS cell with diamond-like grains is low if the VBO at the GBs exceeds 0.4 eV. The VBO at which the η of the CIGS cell with diamond-like grains peaks is found at 0.20–0.27 eV. A favorable VBO mainly depends on the shape of the grains, but it also depends on the NtA. The simulations of the CIGS cells in the substrate and superstrate configurations showed that their performances change if the VBO is varied. This result also implies that the configuration of the CIGS cell is important and the substrate configuration with larger grains in the space-charge region has a considerable advantage if the VBO ranges from 0 eV to 0.2 eV.
Journal: Thin Solid Films - Volume 519, Issue 21, 31 August 2011, Pages 7497–7502