کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1669726 1008888 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemical nucleation and growth of poly-N-Methylpyrrole on copper
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Electrochemical nucleation and growth of poly-N-Methylpyrrole on copper
چکیده انگلیسی

The potentiostatic electropolymerization of poly-N-Methylpyrrole on Cu at 1.5 V, 2.0 V and 2.5 V vs saturated calomel electrode potentials has been carried out to establish the successive steps of polymer coating generation. The chronoamperograms obtained allow the different steps of the nucleation and growth mechanism to be analyzed by fitting the experimental data to the mathematical equations established in the electrocrystallization theory. In all cases a mechanism consisting of a two-dimensional growth at short time followed by a three-dimensional diffusion controlled growth and at longer times a subsequent two-dimensional growth mechanism, with progressive nucleation, is suggested. Scanning electron microscopy micrographs support this mechanism.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thin Solid Films - Volume 519, Issue 8, 1 February 2011, Pages 2387–2392
نویسندگان
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