کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1671562 | 1008920 | 2007 | 8 صفحه PDF | دانلود رایگان |

Undoped and Fe-doped TiO2 nanopowders with Fe/Ti (atomic ratio) precursor concentration ranging from 7% up to 25% have been prepared by the IR laser pyrolysis technique. A sensitized mixture of TiCl4 and Fe (CO)5 was used as titanium and iron precursor, respectively. Reference undoped titania samples with a major concentration of anatase phase (about 90%) were obtained by the same technique by using very high flows of the oxidizing agent (air). The effects of the iron-dopant concentration on the essential structural properties of the resultant powders such as the phase formation, the crystallinity, the average particle size and distributions were systematically investigated by X-ray diffraction, Raman spectroscopy and transmission electron microscopy. The decrease of the TiO2-anatase crystalline phase, the simultaneous increase of the amorphous phase and the decrease in size of particle mean diameter appear as main effects induced by the Fe-dopant concentration.
Journal: Thin Solid Films - Volume 515, Issue 24, 15 October 2007, Pages 8438–8445