کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1672099 | 1008928 | 2008 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Preparation and photoelectrochemical properties of a hybrid electrode composed of polypyrrole encapsulated in highly ordered titanium dioxide nanotube array Preparation and photoelectrochemical properties of a hybrid electrode composed of polypyrrole encapsulated in highly ordered titanium dioxide nanotube array](/preview/png/1672099.png)
We demonstrated in this paper that polypyrrole encapsulated in highly ordered TiO2 nanotubes array (PPy/TiO2 NTs) electrode could be obtained via two steps: (1) electrosynthesis of TiO2 nanotube array in HF solution by anodization method; (2) followed by electropolymerization of pyrrole encapsulated in the TiO2 nanotubes array. The morphological characteristics and structures of PPy/TiO2 NTs electrode were examined by field-emission scanning electron microscopy, X-ray diffraction, and energy dispersive X-ray spectroscopy. The photoelectrochemical properties were studied in a three-electrode cell with 0.5 M Na2SO4 solution as supporting electrolyte. The photocurrent was dramatically enhanced on the PPy/TiO2 NTs electrode, comparing with that on bare TiO2 NTs electrode. A photocurrent density of 1.52 mA cm− 2 and the incident photon to electron conversion efficiency of 73.21% were obtained under an UV illumination of 10 mW cm− 2.
Journal: Thin Solid Films - Volume 516, Issue 23, 1 October 2008, Pages 8663–8667