کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1673898 | 1008954 | 2008 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Microwave-assisted synthesis of indium tin oxide nanocrystals in polyol media and transparent, conductive layers thereof Microwave-assisted synthesis of indium tin oxide nanocrystals in polyol media and transparent, conductive layers thereof](/preview/png/1673898.png)
Aiming at a facile and low-cost liquid phase synthesis of indium tin oxide (ITO), a microwave-assisted preparation in high-boiling, multidentate alcohols (so-called polyols) is evaluated. While heating for 2 h at 200 °C and ambient pressure, transparent ITO suspensions are obtained exhibiting a bright blue color. According to dynamic light scattering, scanning electron microscopy, transmission electron microscopy, X-ray diffraction and Brunauer–Emmett–Teller analysis, as-prepared particles turn out to be single crystalline with an average diameter of 17 nm and a near monodisperse size distribution. Four-point probing of powder pellets reveals a low resistivity (1.1 × 10− 2 Ω cm) of as-prepared In2O3:Sn (5 mol.%). Fourier-transform infrared spectra show a reflectivity in the infrared close to 100%. As a proof of concept, thin layers are deposited on glass plates using a simple solvent evaporation technique. After a certain post-treatment, these layers exhibit a visible transmittance similar to the uncoated glass substrate and a low resistivity (1.2 × 10− 2 Ω cm).
Journal: Thin Solid Films - Volume 516, Issue 21, 1 September 2008, Pages 7437–7442