کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1674277 | 1008961 | 2008 | 8 صفحه PDF | دانلود رایگان |

Hydrogen permeation performance of three thin palladium–copper composite membranes with different thicknesses had been studied between 398 K and 753 K. Hydrogen permeance was obtained up to 2.7 × 10− 6 mol/(m2 s Pa) with an ideal selectivity over 1000 at 753 K. The hydrogen permeation exhibited two different activation energies over the temperature range: lower activation energy of about 9.8 kJ/mol above 548 K, while higher activation energy of about 26.4 kJ/mol below 548 K. After permeation tests, the alloy membranes were characterized by X-ray photoelectron spectroscopy, scanning electron microscopy, energy dispersive X-ray analysis and in situ X-ray diffraction. Palladium segregation on the surface of these palladium–copper alloys may induce changes of hydrogen permeation performance and thus influence the activation energies.
Journal: Thin Solid Films - Volume 516, Issue 8, 29 February 2008, Pages 1849–1856