کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1674277 1008961 2008 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hydrogen transport through thin palladium–copper alloy composite membranes at low temperatures
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Hydrogen transport through thin palladium–copper alloy composite membranes at low temperatures
چکیده انگلیسی

Hydrogen permeation performance of three thin palladium–copper composite membranes with different thicknesses had been studied between 398 K and 753 K. Hydrogen permeance was obtained up to 2.7 × 10− 6 mol/(m2 s Pa) with an ideal selectivity over 1000 at 753 K. The hydrogen permeation exhibited two different activation energies over the temperature range: lower activation energy of about 9.8 kJ/mol above 548 K, while higher activation energy of about 26.4 kJ/mol below 548 K. After permeation tests, the alloy membranes were characterized by X-ray photoelectron spectroscopy, scanning electron microscopy, energy dispersive X-ray analysis and in situ X-ray diffraction. Palladium segregation on the surface of these palladium–copper alloys may induce changes of hydrogen permeation performance and thus influence the activation energies.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thin Solid Films - Volume 516, Issue 8, 29 February 2008, Pages 1849–1856
نویسندگان
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