کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1675548 1008980 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Metallic nickel nanorod arrays embedded into ordered block copolymer templates
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Metallic nickel nanorod arrays embedded into ordered block copolymer templates
چکیده انگلیسی

We report on metallic Nickel nanorods prepared by utilizing a mask of ordered nanostructured hollow channels in a block copolymer matrix. These polymeric templates were formed by a self organized process in block copolymer supramolecular assemblies. Nickel was filled into with two different techniques, electrodeposition and washing in. We monitor the formation process of these nanorods by means of atomic force microscopy and synchrotron radiation soft X-ray based photoelectron emission microscopy. The oxidation state of the nickelrods is evaluated with X-ray absorption spectroscopy and X-ray photoelectron spectroscopy at the Ni L edges and lateral distributions of the Ni nanorods were detected with micrometer resolved X-ray absorption spectroscopy. The finding is that the Ni rods were metallic despite their preparation under ambient conditions, inside the particles no hints for NiO complexes were found. This indicates that the polymer protects Ni nanoparticles against oxidation.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thin Solid Films - Volume 515, Issue 16, 4 June 2007, Pages 6552–6556
نویسندگان
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