کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
191895 459730 2010 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and electrochemical performance of lithium vanadium oxide nanotubes as cathodes for rechargeable lithium-ion batteries
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Synthesis and electrochemical performance of lithium vanadium oxide nanotubes as cathodes for rechargeable lithium-ion batteries
چکیده انگلیسی

A new kind of cathode materials for rechargeable lithium-ion batteries, lithium vanadium oxide nanotubes synthesized by a combined sol–gel reaction and hydrothermal treatment procedure is reported in this paper. SEM, TEM, XRD and XPS techniques were performed to investigate the morphology and structure of the resulting materials. The results confirmed that the synthetic materials are composed of uniformly open-ended multiwalled nanotubes with a length from 1 to 3 μm. The inner and the outer diameters of the obtained nanotubes vary from 30 to 50 nm and 50 to 120 nm, respectively. The electrochemical performance as a cathode material was examined and evaluated by cyclic voltammetry, galvanostatic charge–discharge cycling and AC impedance spectroscopy techniques. The results indicated that the resultant lithium vanadium oxide nanotubes have a high initial discharge capacity of 457 mAh g−1 in the potential range of 1.0–4.0 V (vs. Li/Li+) and good cycling performance. The improved electrochemical performance of the products should be due to its special one-dimensional multiwalled tubular structure and the contribution of lithium-ions.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 55, Issue 7, 28 February 2010, Pages 2536–2541
نویسندگان
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