کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
210420 | 461710 | 2012 | 4 صفحه PDF | دانلود رایگان |

A transesterification reaction of esters from soybean oil with ethanol assisted by low-frequency ultrasound (20 kHz) was performed in the presence of a potassium hydroxide catalyst. The effects of the following variables on the reaction performance were studied simultaneously through a full two-level factorial design 23: the concentration of the catalyst, the oil:ethanol molar ratio and the sonication time. The three investigated factors significantly affected the yield. Further experimentation was performed using a three-step reaction. An ethyl ester yield of approximately 98% was attained in the third step. The physicochemical properties of the products were compared with the technical limits of biodiesel, and the results suggest that the ultrasound-assisted ethanol transesterification reaction could be a viable and efficient method for the production of quality biodiesel from soybean oil.
► A transesterification of esters from soybean oil with ethanol assisted by ultrasound was performed.
► Ethanolysis assisted by ultrasound allows for good conversion with a sonication time of 360 s.
► Ultrasonic irradiation can be an efficient method of producing quality biodiesel from soybean oil and ethanol.
Journal: Fuel Processing Technology - Volume 95, March 2012, Pages 33–36