کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
213461 | 462103 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dissolution kinetics of galena in acetic acid solutions with hydrogen peroxide
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
The kinetics of leaching lead from galena in acetic (ethanoic) acid solutions with hydrogen peroxide are investigated with regard to stirring speed, temperature and concentration of HAc and H2O2 concentration. Oxidation of galena with H2O2 to produce lead sulphate which dissolves by complexing Pb2+ with acetate anion (PbCH3COO+ and Pb(CH3COO)2). Results indicate that the rate of galena dissolution is controlled by a surface chemical reaction with an apparent activation energy is 65.6 kJ mol− 1 in the temperature range 30–70 °C. Both HAc and H2O2 affect the rate of extraction of lead as an acetate complex. The order of reaction was 0.79 and 0.31 for H2O2 and HAc concentrations, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Hydrometallurgy - Volume 89, Issues 3–4, December 2007, Pages 189–195
Journal: Hydrometallurgy - Volume 89, Issues 3–4, December 2007, Pages 189–195
نویسندگان
Salih Aydoğan, Ali Aras, Gökhan Uçar, Murat Erdemoğlu,