کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4477112 1622769 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Pyrolysis of spill oils adsorbed on zeolites with product oils recycling
موضوعات مرتبط
مهندسی و علوم پایه علوم زمین و سیارات اقیانوس شناسی
پیش نمایش صفحه اول مقاله
Pyrolysis of spill oils adsorbed on zeolites with product oils recycling
چکیده انگلیسی

Experimentally, a feasibility study for adsorption and catalytic pyrolysis of spill oils on Cu/ZSM-5 for recycling of light oils has been conducted in the present work. The adsorption and pyrolysis of model compounds such as heptane, toluene, and diesel (to stimulate the spill oils) on Cu/ZSM-5 have been investigated on a continuous fixed-bed reactor. By component fitted X-ray absorption near edge structural (XANES) spectroscopy, catalytic active species such as metallic copper (Cu) (77–84%) and Cu2O (6–7%) are found in the channels of ZSM-5 during pyrolysis of heptane or toluene. Pyrolysis of diesel effected by Cu/ZSM-5 yields gas (C1–C5) (32%) and light oil (68%) that can be used as auxiliary fuels.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Marine Pollution Bulletin - Volume 57, Issues 6–12, 2008, Pages 895–898
نویسندگان
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