A novel two-step coprecipitation process using Fe(III) and Al(III) for the removal and immobilization of arsenate from acidic aqueous solution

Lime neutralization and coprecipitation of arsenate with iron is widely practiced for the removal and immobilization of arsenic from mineral processing effluents. However, the stability of the generated iron-arsenate coprecipitate is still of concern. In this work, we developed a two-step coprecipitation process involving the use of iron and aluminum and tested the stability of the resultant coprecipitates. The two-step Fe–As–Fe or Fe–As–Al coprecipitation process involved an initial Fe/As = 2 coprecipitation at pH4 to remove arsenic from water down to 0.25 mg/L, followed by introduction of iron or aluminum (Fe/As = 2, Al/As = 1.5 or 2). The two-step coprecipitates showed higher stability than traditional Fe/As = 4 coprecipitate under both oxic and anoxic conditions. Leaching stability was enhanced when aluminum was applied in the second step. The use of aluminum in the second step also inhibited microbial mediated arsenate reduction and arsenic remobilization. The results suggest that the two-step coprecipitation process is superior to conventional coprecipitation methods with respect to the stability of the generated arsenic-bearing solid waste. The use of Al in the second step is better than Fe to enhance the stability. This work may have important implications to the development of new technologies for efficient arsenic removal from hydrometallurgical solutions and safe disposal in both oxic and anoxic environment.

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► A new coprecipitation process for arsenic removal/immobilization from water was developed.
► This process involves an arsenic removal step and a stability improvement step.
► Arsenic can be removed to sub-ppm level and the solid shows considerably high stability.