The heterogeneous coagulation and flocculation of brewery wastewater using carbon nanotubes

Coagulation and flocculation treatment processes play a central role in the way wastewater effluents are managed. Their primary function is particle removal that can impart colour to a water source, create turbidity, and/or retain bacterial and viral organisms. This study was carried out to investigate whether carbon nanotubes (CNTs) can be used as heterogeneous coagulants and/or flocculants in the pretreatment of brewery wastewater. A series of experiments were conducted in which the efficiencies of pristine and functionalised CNTs were compared with the efficiency of traditional ferric chloride in a coagulation/flocculation process. Turbidity and chemical oxygen demand (COD), including the zeta potential were used to monitor the progress of the coagulation/flocculation process. Both pristine and functionalised CNTs demonstrated the ability to successfully coagulate colloidal particles in the brewery wastewater. Overall, ferric chloride was found to be a more effective coagulant than both the pristine and functionalised CNTs.

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► Different chemicals were compared for the coagulation and flocculation of brewery wastewater.
► Carbon nanotubes (CNTs) can be used as heterogeneous coagulants in the pretreatment of brewery wastewater.
► Ferric chloride was a more effective coagulant than both functionalised and pristine CNTs.