کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4485535 | 1316956 | 2007 | 10 صفحه PDF | دانلود رایگان |

The chemical degradation of the endocrine disrupting chemical, butylated hydroxyanisole (BHA), was investigated by different treatment processes including ultraviolet (UV) irradiation, ozonation (O3), and UV/O3. O demethylation, dimerization, and oxidation have been found to be the main degradation mechanisms. A systematic decay pathway was proposed based on ten identified intermediates in the studied processes, including a unique pathway leading to the formation of precipitates in the ozonation process. An unconventional minimum-type variation of BHA decay rate constants from acidic to caustic range has been found for both ozonation and UV/O3 processes. The precipitates formed during ozonation can be removed during the process to optimize the treatment, while the UV/O3 process can offer a relatively fast and clean process to degrade BHA and its associated intermediates.
Journal: Water Research - Volume 41, Issue 4, February 2007, Pages 765–774