On the anatomy of magma chamber and caldera collapse: The example of trachy-phonolitic explosive eruptions of the Roman Province (central Italy)

• Trachy-phonolitic eruptions of the Roman Province show juvenile textural changes
• Juvenile textural changes evidence thermally and volatile-zoned magma chambers
• Juvenile textural zoning evidences changing vent geometries during caldera collapse
• Pre-eruptive thermal- and volatile-zoning controls differentiation of potassic magmas
• We characterize major potassic eruptions relevant for Quaternary tephrostratigraphy

Textural and compositional features of pyroclastic products erupted during caldera-forming events often reveal the tapping of different portions of variably zoned magma chambers due to changing geometries of the conduit/vent systems. Here we report on ultrapotassic trachytic–phonolitic explosive eruptions of the Roman Province (central Italy), which show remarkable changes of textural features and glass compositions in the juvenile material, even if the bulk chemical composition is essentially constant. In each example, the lower eruption sequence contains whitish, crystal-poor (leucite-free), highly vesicular pumice, emplaced by early Plinian fallout and/or pyroclastic currents; upsection, the eruption sequence contains black, low porphyritic (sanidine + leucite-bearing), moderately vesicular, scoria or spatter, emplaced by major pyroclastic flows (red tuff with black scoria) and associated co-ignimbrite, coarse lithic-rich breccias. This suggests a shift from a central feeder conduit, tapping the central part of the magma chamber, to a ring fracture vent system, tapping the peripheral portions of the magma chamber, during caldera collapse. Key features of these evacuating magma chambers are the thermal and volatile concentration (Xvol) gradients that produce the observed textural and compositional spectrum of trachy-phonolitic rock types. In particular, the degrees of freedom during the crystallization of these ultrapotassic magmas are increased by the variation of the leucite stability field at different PH2O conditions. Both leucite-free and leucite-bearing differentiated ultrapotassic rock types can be produced in the course of individual eruptions, as a result of pre-eruptive conditions in the feeder magma, with no need to invoke different differentiation suites related to mantle source heterogeneities of parental magmas.