Comparative study of the application of chelating resins for rare earth recovery

The adsorption properties of chelating ion exchange resins containing mixed sulfonic/phosphonic (SP), aminophosphonic (AP) or iminodiacetic (IDA) acid functional groups were investigated towards the rare earth elements (REE). The aim of this work was to determine the potential for such resins to assist in the isolation of a mixed rare earth product under conditions relevant to the hydrometallurgical processing of rare earth containing minerals. The selectivity of the resins towards La, Sm and Ho, versus the common impurity metals; Al, Fe and Th, was determined in sulfuric acid media. The chelating resins all displayed a similar selectivity with Fe and Th adsorbed in preference to the REE and Al (i.e. Th ≃ Fe ≫ REE ≃ Al). The IDA resin displayed a far superior performance compared to both phosphonic resins (SP and AP) as well as a strong acid cation exchange resin for the adsorption of REE in the presence of very high Na or Ca concentrations. Equilibrium and kinetic adsorption isotherms for La were measured and successfully modelled with all resins, and the elution characteristics of selected resins investigated in both batch and column operation. A number of areas were identified where these resins could be exploited to provide an advantage in the hydrometallurgical processing of REE.