کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5466563 | 1398905 | 2016 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Sputter-deposited 20Â mol% gadolinia-doped ceria films on 8Â mol% yttria-stabilized zirconia tapes for improved electrochemical performance
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
20 mol% Gd-doped ceria (20GDC) films on poly-crystalline 8 mol% yttria-stabilized zirconia tapes (8YSZt) were rf-sputtered through a lab-made 20GDC oxide target and investigated with regard to the oxygen non-stoichiometry, chemical composition, and morphology of the films. The as-deposited 20GDC dense films with various oxidation states of Ce ions were obtained by the deposition conditions of 200 W. The interpretation of chemical states of cerium (Ce) in the as-deposited 20GDC films showed the mixing tetravalent (Ce4 +)/trivalent (Ce3 +) states of Ce4O7 phase. After the annealing process in air at 900 °C for 2 h, results of X-ray diffraction and X-ray photoelectron spectroscopy showed that the fully oxidized 20GDC phase with a cubic fluorite structure was obtained. Columnar grain features of annealed films were examined normal to â¨200â© of 8YSZ substrates by quantitative transmission electron microscopy techniques. The conductivity measurement results provided that the sputtered-20GDC films on 8YSZ tape can be used as solid electrolytes for improved electrochemical performance in a solid oxide fuel cell system at the operation temperatures of 500 - 700 °C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thin Solid Films - Volume 618, Part A, 1 November 2016, Pages 202-206
Journal: Thin Solid Films - Volume 618, Part A, 1 November 2016, Pages 202-206
نویسندگان
Yu-Lin Kuo, Sung-En Lin, Wen-Cheng J. Wei, Yu-Ming Su,