Clay-mineral compositions of sediments in the Gaoping River-Sea system: Implications for weathering, sedimentary routing and carbon cycling

Small mountainous rivers (SMRs) play a crucial role in the global sediment and carbon cycle by rapid transfer of huge particulate and dissolved loads into the sea. Gaoping river-sea system is a good representative of SMRs in Oceania, having an extreme high denudation rate (15,000 t km− 2 yr− 1) and a high burial efficiency of terrestrial particulate organic carbon (POC) in the Gaoping submarine canyon (GPSC). However, it is contentious whether silicate weathering or POC burial plays more important role in long-term carbon cycling in such a high active orogen. Clay minerals of fluvial sediments not only act as an important carrier of POC, but also encode valuable information of weathering regimes on land and dispersal routes in the seas. To uncover these informations, surface and core sediments are systematically collected from the Gaoping river-sea system for clay-mineral analysis. Comparative studies are carried out on the basis of new results and vast published data to better understand weathering processes and products in Oceanian islands and Southeast Asian continent. We find that clay-mineral compositions in the Gaoping River (GPR) and other Taiwan rivers are a legacy from provenance rocks in the alpine reach, characterized by predominant illite and chlorite and limited compositional change throughout the river courses. These sharply contradict the downstream increase in compositional complexity (rich in kaolinite and smectite) and chemical weathering intensity in Southeast Asian large rivers because of strong hydrolysis and active sediment recycling at the lowland reach with extensive floodplains. High consistency of clay-mineral compositions is also observed in the interior and exterior of GPSC. Careful examination shows that a slight offshore decrease in cumulative illite and chlorite content is accompanied by a slight increase in exotic clay-mineral inputs by ocean circulations. The combination of this finding with previously reported data on the offshore change in δ13Corg and Δ14Corg values suggests that petrogenic POC predominates in the river-dominated Gaoping continental margin with high preservation efficiency due to its tight bandage with clay minerals. Moreover, a tardy response of chemical weathering fluxes to high elevated physical erosion rates is remarkably examined in the Oceanian and global river gauging data. We therefore postulate that rapid transfer and high burial efficiency of terrestrial POC in the tectonically active high-standing islands and their adjacent continental margins play much more important role in the long-term carbon cycle than silicate weathering.