Rheological measurements of Na-bentonite and sepiolite particles in the presence of tetradecyltrimethylammonium bromide, sodium tetradecyl sulfonate and Brij 30 surfactants

The effects of cationic tetradecytrimethylammonium bromide (TDTMABr), anionic sodium tetradecyl sulfonate (NaTDS) and nonionic Brij 30 surfactants on the electrokinetic and rheological properties of Na-bentonite and sepiolite suspensions have been investigated. It has been found from the zeta potential measurements that the negative surface charge of Na-bentonite and sepiolite has become positive in the presence of 7.5 × 10−3 M and 1.0 × 10−3 M TDTMABr, respectively. As the concentration of NaTDS is increased in the suspension, the zeta potential value of Na-bentonite does not change significantly, but that of sepiolite decreases gradually. Na-bentonite–surfactant suspensions show a thixotropic behavior, on the other hand sepiolite–surfactant suspensions display a rheopexic or thixotropic behavior depending on the surfactant concentration. All clay–surfactant suspensions follow a Bingham type flow behavior. The surfactant concentration leads to significant changes in the plastic viscosity (ηpl) values of sepiolite–surfactant suspensions, on the contrary of Na-bentonite–surfactant systems. Some shifts in the peak positions have been observed in the FTIR spectra of samples, which have provided evidence about the interactions between clay particles and surfactant molecules. This study shows that the suspensions having the desired zeta potential and ηpl values and thixotropic or rheopexic behaviors can be obtained using different clay–surfactant mixtures.

Na-bentonite–tetradecyltrimethylammonium bromide (TDTMABr) suspensions show a thixotropic behavior in the presence of different surfactant concentrations, on the other hand sepiolite–TDTMABr suspensions display a rheopexic behavior or a thixotropic behavior.Figure optionsDownload as PowerPoint slideHighlights
► Surfactants may affect the electrokinetic properties of clay suspensions.
► Surfactants can be used to control the viscosity behavior of sepiolite suspensions.
► Suspensions show rheopexic or thixotropic behaviors depending on clay type.
► There are some shifts in the FTIR peak positions of clays after the interactions.
► Clay–surfactant suspensions are of a Bingham type flow behavior.