کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6358542 | 1315630 | 2014 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Photocatalytic splitting of seawater effected by (Ni-ZnO)@C nanoreactors
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
علوم زمین و سیارات
اقیانوس شناسی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
Novel photocatalysts i.e., metallic nickel and zinc oxide nanoparticles embedded in the carbon-shell ((Ni-ZnO)@C) have been used for photocatalytic splitting of seawater to generate H2. The (Ni-ZnO)@C core-shell nanoparticles having the Zn/Ni ratios of 0-3 were prepared by carbonization of Ni2+- and Zn2+-β-cyclodextrin at 673 K for 2 h. To increase the collision frequency of water and photoactive sites within the carbon-shell, Ni and ZnO are partially etched from the (Ni-ZnO)@C core-shell to form yolk-shell nanoparticles with a H2SO4 solution (2 N). By X-ray diffraction spectroscopy, mainly Ni and ZnO crystallites are observed in the core- and yolk-shell nanoparticles. The sizes of the Ni and ZnO in the (Ni-ZnO)@C nanoreactors are between 7 and 23 nm in diameters determined by TEM and small angel scattering spectroscopy. Under a 5-h UV-Vis light irradiation, 5.01 μmol/hgcat of H2 are yielded from photocatalytic splitting of seawater effected by (Ni-ZnO)@C nanoreactors.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Marine Pollution Bulletin - Volume 85, Issue 2, 30 August 2014, Pages 696-699
Journal: Marine Pollution Bulletin - Volume 85, Issue 2, 30 August 2014, Pages 696-699
نویسندگان
T.-C. Yang, F.-C. Chang, H. Paul Wang, Y.-L. Wei, C.-J. Jou,