کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6444586 1640390 2013 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Dissolution kinetics and biodurability of tremolite particles in mimicked lung fluids: Effect of citrate and oxalate
ترجمه فارسی عنوان
سینتیک انحلال و بازیافت ذرات ترمولیت در مایعات مضر ریه: اثر سیترات و اگزالات
موضوعات مرتبط
مهندسی و علوم پایه علوم زمین و سیارات زمین شناسی
چکیده انگلیسی
The effect of citrate and oxalate on tremolite dissolution rate was measured at 37 °C in non-stirred flow-through reactors, using modified Gamble's solutions at pH 4 (macrophages), 7.4 (interstitial fluids) and 5.5 (intermediate check point) containing 0, 0.15, 1.5 and 15 mmol L−1 of citrate or oxalate. The dissolution rates calculated from Si concentration in the output solutions without organic ligands depend on pH, decreasing when the pH increases from −13.00 (pH 4) to −13.35 (pH 7.4) mol g−1 s−1 and following a proton-promoted mechanism. The presence of both ligands enhances dissolution rates at every pH, increasing this effect when the ligand concentration increases. Citrate produces a stronger effect as a catalyst than oxalate, mainly at more acidic pHs and enhances dissolution rates until 20 times for solutions with 15 mmol L−1 citrate. However, at pH 7.4 the effect is lighter and oxalate solutions (15 mmol L−1) only enhances dissolution rates eight times respect to free organic ligand solutions. Dissolution is promoted by the attack to protons and organic ligands to the tremolite surface. Magnesium speciation in oxalate and citrate solutions shows that Mg citrate complexes are more effective than oxalate ones during the alteration of tremolite in magrophages, but this tendency is the opposite for interstitial fluids, being oxalate magnesium complexes stronger. The biodurability estimations show that the destruction of the fibers is faster in acidic conditions (macrophages) than in the neutral solutions (interstitial fluid). At pH 4, both ligands oxalate and citrate reduce the residence time of the fibers with respect to that calculated in absence of ligands. Nevertheless, at pH 7.4 the presence of ligands does not reduce significantly the lifetime of the fibers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Asian Earth Sciences - Volume 77, 15 November 2013, Pages 318-326
نویسندگان
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