Seismic slip recorded in tourmaline fault mirrors from Elba Island (Italy)

Micro and nanostructural investigations indicate the occurrence of thermally-activated processes, involving both interstitial goethite and tourmaline. In particular, close to the principal slip surface, goethite is completely decomposed, and produced an amorphous porous material, with local topotactic recrystallization of hematite. Tourmaline clasts are typically characterized by strongly lobate boundaries, indicative of reaction and partial decomposition at grain boundaries. TEM observations revealed the occurrence of tourmaline nanograins, a few tens of nm in size, characterized by rounded shape and fading amorphous boundaries, that cannot be obtained by brittle processes. Lastly, the peculiar interlobate microstructure of the mirror surface is interpreted as the result of grain boundary recrystallization processes taking place by deformation at high-T conditions. Our results show that tourmaline fault mirrors recorded localized high-T processes triggered by frictional heating and can be therefore considered as reliable traces of ancient earthquakes.