کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6611714 | 459565 | 2015 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Engineering graphene aerogels with porous carbon of large surface area for flexible all-solid-state supercapacitors
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Graphene nanosheets, typical two-dimensional sp2 hybridized carbon materials, are gaining increasingly attention in many fields due to their excellent electrical and large surface area. As electrode materials for supercapacitors, however, intrinsic large surface area of graphene is generally suppressed because of the unexpected re-stacking upon the processes. The mostly used method for address this issue is to insert “spacers” between into graphene interlayers, including metal oxides and other carbon materials. Since the structure instability limits the use of metal oxides, carbon materials play the main role in prohibiting graphene restacking. Herein, we synthetized a novel porous carbon with the lager surface area of 2211Â m2Â gâ1 for achieving three-dimensional (3D) graphene/porous carbon (LGN/PC) aerogel through the facile hydrothermal method. The resulting binder-free electrode based on the LGN/PC shows excellent electrochemical performance in three-electrode cell in the 6Â M KOH aqueous electrolyte, with the highest capacity observed up to 410Â FÂ gâ1 at 0.1Â AÂ gâ1. Moreover, the all-solid-state supercapacitor based on the 3D LGN/PC exhibits no significant capacitance loss after 10,000 cycles at a current density of 5Â AÂ gâ1 and no capacity loss was observed upon bending.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 165, 20 May 2015, Pages 92-97
Journal: Electrochimica Acta - Volume 165, 20 May 2015, Pages 92-97
نویسندگان
Tian-Tian Chen, Wei-Li Song, Li-Zhen Fan,