کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
75331 49113 2009 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Crosslinked TS-1 as stable catalyst for the Beckmann rearrangement of cyclohexanone oxime
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Crosslinked TS-1 as stable catalyst for the Beckmann rearrangement of cyclohexanone oxime
چکیده انگلیسی

Crosslinked TS-1 zeolite materials have been studied in the gas phase Beckmann rearrangement reaction of cyclohexanone oxime to ε-caprolactam. Crosslinking of the zeolite particles resulted in the formation of an additional mesoporosity leading to increased activity in the Beckmann rearrangement reaction. The increased activity can be correlated with the newly created mesopore surface. Possibly more important, together with increased catalytic activity of the materials, the deactivation behavior of the catalysts is very significantly improved.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 117, Issues 1–2, 1 January 2009, Pages 228–232
نویسندگان
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