کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7841892 1506506 2018 34 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermodynamic, kinetic and mechanistic approach to the corrosion inhibition of carbon steel by new synthesized amino acids-based surfactants as green inhibitors in neutral and alkaline aqueous media
ترجمه فارسی عنوان
رویکرد ترمودینامیک، جنبشی و مکانیکی به مهار خوردگی فولاد کربن با سورفکتانت های سنتز شده با آمینو اسید های جدید به عنوان بازدارنده های سبز در محیط های آبی خنثی و قلیایی
کلمات کلیدی
سورفکتانت های مبتنی بر آمینو اسید، مهار کننده ها، سدیم کلرید، هیدروکسید سدیم، خوردگی، فولاد کربن،
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
چکیده انگلیسی
The inhibiting power of three synthesized amino acids based-surfactant molecules, namely, sodium N-dodecyl asparagines (AS), sodium N-dodecylhistidine (HS) and sodium N-dodecyltryptophan (TS) on the dissolution of carbon steel was inspected in 0.5 M NaCl and 05 M NaOH solutions at 25 °C. The methods employed in this work were weight-loss (WL), potentiodynamic polarization (PP) and electrochemical impedance spectroscopy (EIS). The chemical structures of the synthesized surfactants were confirmed by FT-IR and 1HNMR. The inhibition efficiencies were found to increase as the surfactants concentrations increase, while decreasing with increasing the concentration of the corrosive media (NaCl & NaOH) and temperature. Results obtained from the different techniques revealed that the inhibition efficiency of the compound TS was higher than those of both AS and HS. The inhibition efficiencies of the synthesized surfactants were declined in terms of strong adsorption of surfactants on the surface of carbon steel and forming a protective film and such adsorption was found to obey Langmuir isotherm. Both thermodynamic and kinetic parameters were evaluated which support the mechanism of physical adsorption of the inhibitors. The tested surfactants were found to act as mixed-type inhibitors with anodic predominance. The surface morphology of the carbon steel surface was examined by scanning electron microscopy (SEM). The inhibitory mechanism of carbon steel corrosion was suggested. Results obtained from all employed methods are consistent with each other.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 265, 1 September 2018, Pages 276-291
نویسندگان
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